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Runaway Reaction Relief Calculator

AIChE/DIERS · API RP 520/521

Runaway Reaction Relief Calculator
Calculates relief requirements for exothermic runaway reactions using AIChE/DIERS methodology. Determines required vent area, self-heat rate, TMR, and relief capacity per API 520 Part II for tempered, hybrid, and gassy systems.

Reaction Parameters

ft³
BTU/lb-mol
°F
mol/ft³
1/hr

Vessel & Liquid Properties

lb
BTU/lb-°F
BTU/lb
ft³
%
lb/ft³
Typical: Cp = 0.4-0.6 BTU/lb-°F, λ = 150-200 BTU/lb

Relief Device Parameters

psig
psig
g/mol
Cp/Cv
-
API 520 Kd Values:
Conventional PSV: 0.975 | Balanced Bellows: 0.85
Rupture Disk (alone): 0.62 | Pilot Operated: 0.975

About This Calculator

Emergency relief sizing for runaway reactions per AIChE/DIERS methodology and API RP 520/521.

Key Parameters:

  • Self-Heat Rate: °F/min from Q/(m×Cp)
  • TMR: Time to Maximum Rate (adiabatic)
  • Vapor Rate: lb/hr from Q/λ

System Classification:

  • Tempered: Vapor-only, use API 520
  • Gassy: Two-phase, use DIERS HEM

Frequently Asked Questions

What is DIERS methodology for reaction relief sizing?

DIERS (Design Institute for Emergency Relief Systems) methodology calculates relief requirements for runaway exothermic reactions. It determines required vent area, self-heat rate, and time to maximum rate (TMR) for tempered, hybrid, and gassy systems per API 520 Part II.

What is the difference between tempered and gassy relief systems?

Tempered systems produce vapor-only relief where boiling absorbs the reaction heat, and standard API 520 sizing applies. Gassy systems produce non-condensable gas requiring two-phase venting, which uses the DIERS Homogeneous Equilibrium Model (HEM) for sizing.

What is self-heat rate in runaway reaction analysis?

Self-heat rate is the temperature rise per unit time (°F/min) caused by an exothermic reaction under adiabatic conditions. It is calculated from the heat generation rate divided by the product of reacting mass and specific heat capacity.

What discharge coefficient (Kd) values does API 520 specify?

API 520 specifies Kd = 0.975 for conventional PSVs and pilot-operated valves, Kd = 0.85 for balanced bellows valves, and Kd = 0.62 for rupture disks used alone.