1. Cathodic Protection Principles
Cathodic protection (CP) is an electrochemical technique that prevents corrosion of a metal surface by making it the cathode of an electrochemical cell. For buried steel pipelines, CP is the primary method for controlling external corrosion and is required by federal regulation (49 CFR 192 for gas, 49 CFR 195 for hazardous liquids).
Electrochemical Basis
Why Both Coating and CP Are Needed
Coating and cathodic protection work synergistically. The coating reduces current demand by preventing electrolyte contact with most of the steel surface. CP protects the pipe at coating holidays (bare spots, damage) where corrosion would otherwise occur. Without coating, the CP current demand would be prohibitively high. Without CP, even small coating defects would allow localized corrosion to proceed unchecked.
Coating Only
Incomplete Protection
Coating defects, holidays, and age-related degradation leave bare steel exposed. Localized corrosion at defects can be severe.
CP Only
Impractical
Current density for bare steel: 1-5 mA/ft2. For a 12-inch, 50-mile pipeline, this requires enormous power and anode beds.
Coating + CP
Complete Protection
Good coating reduces demand to 0.01-0.1 mA/ft2. CP protects at holidays. Industry standard approach per NACE SP0169.
2. CP Criteria
NACE SP0169 (formerly RP0169) defines several criteria for establishing adequate cathodic protection. The most widely used is the -850 mV Cu/CuSO4 criterion. Understanding the basis and limitations of each criterion is essential for accurate interpretation of survey data.
Primary Criterion: -850 mV
Alternative Criteria
| Criterion | NACE SP0169 Ref | Description | When Used |
|---|---|---|---|
| -850 mV | 6.2.2.1 | Negative potential of -850 mV or more | Most common, general use |
| 100 mV Shift | 6.2.2.2 | 100 mV polarization from native potential | When -850 criterion cannot be met, high-resistivity soils |
| -950 mV | 6.2.2.3 | More negative criterion for SRB environments | Anaerobic soils, sulfate-reducing bacteria |
| E-log-I | 6.2.2.3 | Net protective current from E-log-I curve | Research, interference analysis |
Overprotection Concerns
While adequate protection requires sufficiently negative potentials, excessive cathodic polarization (overprotection) can cause several problems. Potentials more negative than -1200 mV Cu/CuSO4 can cause cathodic disbondment of coatings, generate hydrogen at the steel surface (risking hydrogen embrittlement of high-strength steels), and waste CP current. NACE SP0169 recommends limiting potentials to no more negative than -1200 mV for most steels and coatings.
3. Measurement Techniques
Accurate pipe-to-soil potential measurement is the foundation of all CP assessment. Measurement errors from poor technique can easily exceed 100 mV, which is the difference between adequate and inadequate protection in many cases.
Basic Measurement Setup
Reference Electrodes
| Type | Potential vs SHE | Equivalent -850 CSE | Application |
|---|---|---|---|
| Cu/CuSO4 (CSE) | +318 mV | -850 mV | Standard for buried pipelines |
| Ag/AgCl | +222 mV | -754 mV | Marine and brackish water |
| Zinc | -763 mV | +231 mV | Permanent buried reference |
| SHE | 0 mV | -532 mV | Laboratory standard |
4. IR Drop Correction
IR drop is the single largest source of error in pipe-to-soil potential measurements. It is the voltage gradient in the soil between the pipe surface and the reference electrode, caused by CP current flowing through the soil resistance. IR drop always makes readings appear more negative (more protected) than the pipe actually is.
IR Drop Magnitude
Correction Methods
| Method | Technique | Accuracy | Limitations |
|---|---|---|---|
| Instant-OFF | Interrupt CP current, read within 0.1-1 s | High | Requires current interrupter at all rectifiers |
| Coupon | Measure potential on disconnected coupon | Very high | Point measurement only, requires coupon installation |
| Reference Electrode Spacing | Multiple readings at varying distances | Moderate | Time-consuming, requires clear ground |
| Calculation | Estimate IR from current and soil resistivity | Low | Too many unknowns for reliable correction |
5. Close-Interval Surveys (CIS)
A close-interval survey (CIS), also called close-interval potential survey (CIPS), measures pipe-to-soil potentials at closely spaced intervals (typically 2.5-5 feet) along the entire pipeline. It is the most comprehensive tool for evaluating the effectiveness of cathodic protection and identifying areas of concern. CIS methodology is defined in NACE SP0207.
CIS Methodology per NACE SP0207
Interpreting CIS Data
- Uniform OFF potentials: Indicate good coating and well-distributed CP. Typical of new or well-maintained systems.
- Localized positive excursions: Suggest coating damage, shielding (rock shield, casings), or insufficient CP current. These are the highest priority for investigation.
- High IR drop areas: Large difference between ON and OFF indicates coating holidays with high current demand. May indicate corrosion activity.
- Gradual ON potential decline: Between test stations indicates current attenuation along the pipeline. May need additional anode installation.
- Interference patterns: Cyclic or step-change patterns may indicate stray current from foreign pipelines, transit systems, or mining operations.
6. Coating Assessment from CP Data
CP survey data provides indirect information about coating condition. While direct inspection (excavation) is the definitive assessment, survey data patterns can identify areas of concern and prioritize direct examination locations.
Coating Condition Indicators
| Indicator | Good Coating | Degraded Coating | Failed Coating |
|---|---|---|---|
| IR Drop | <30 mV, uniform | 30-80 mV, variable | >80 mV, highly variable |
| ON-OFF Spread | Consistent along route | Moderate variation | Large swings, localized peaks |
| Current Demand | <0.1 mA/ft2 | 0.1-1.0 mA/ft2 | >1.0 mA/ft2 |
| Coating Resistance | >50,000 ohm-ft2 | 5,000-50,000 ohm-ft2 | <5,000 ohm-ft2 |
Coating Types and Expected Life
| Coating Type | Expected Life | Degradation Mode | CP Compatibility |
|---|---|---|---|
| Fusion-Bonded Epoxy (FBE) | 30-50 years | Cathodic disbondment at holidays | Excellent |
| Polyethylene (PE) | 40-60 years | Mechanical damage, soil stress cracking | Good (can shield CP if disbonded) |
| Coal Tar Enamel | 20-40 years | Embrittlement, cracking | Good |
| Tape Wrap | 15-25 years | Adhesion loss, tenting, shielding | Poor (shields CP when disbonded) |
7. Soil Effects on CP
Soil properties significantly affect both the corrosion rate of bare steel and the performance of cathodic protection systems. Soil resistivity is the single most important soil parameter, as it affects current distribution, IR drop magnitude, and corrosion severity.
Soil Resistivity Classification
| Resistivity (ohm-cm) | Corrosivity | CP Current Demand | Common Soil Types |
|---|---|---|---|
| <1,000 | Very Corrosive | Very High | Salt marsh, marine clay, contaminated |
| 1,000-2,000 | Severe | High | Clay, wet silt, brackish water table |
| 2,000-5,000 | Corrosive | Moderate | Loam, moist clay, alluvial deposits |
| 5,000-10,000 | Moderate | Low | Sandy clay, dry silt, gravel |
| >10,000 | Low | Very Low | Dry sand, rock, caliche |
8. Data Analysis Methods
Statistical Analysis of CIS Data
Trend Analysis
Comparing CIS data from successive surveys reveals trends in CP system performance and coating degradation. Key indicators include declining OFF potentials at specific locations (indicating increasing corrosion activity), increasing IR drop variability (coating degradation), and systematic shifts in potential profiles (rectifier output changes or anode depletion).
- Year-over-year comparison: Plot OFF potentials from multiple survey years on the same distance axis. Locations showing progressive positive shift warrant investigation.
- Seasonal effects: Soil moisture and temperature affect resistivity. Surveys performed in dry seasons may show more positive readings than wet-season surveys. Normalize for season when comparing data.
- Interference detection: Dynamic stray current from DC transit or mining operations creates time-varying interference. Use 24-hour recordings at suspect locations to characterize interference patterns.
9. Troubleshooting CP Problems
Common Issues and Solutions
| Problem | Symptom in CIS Data | Root Cause | Solution |
|---|---|---|---|
| Shielded pipe | Low OFF potential despite high ON | Disbonded coating, rock shield, or casing prevents CP current from reaching steel | Excavate, remove shielding, recoat |
| Insufficient current | Gradual decline in potential between test stations | Anode depletion, high coating demand, insufficient rectifier output | Increase rectifier output, add anodes, repair coating |
| Interference | Cyclic or step-change potential patterns | Foreign CP system or DC transit current | Interference bond, drainage, coordination with foreign operator |
| Broken wire | Abrupt potential change at specific location | Damaged test lead or broken pipe-to-anode connection | Locate and repair break |
| Overprotection | Very negative potentials (< -1200 mV OFF) | Excessive rectifier output, close proximity to anode bed | Reduce output, add resistance, relocate anodes |
10. Industry Standards
| Standard | Title | Relevance |
|---|---|---|
| NACE SP0169 | Control of External Corrosion on Underground or Submerged Metallic Piping Systems | Primary CP criteria and design standard |
| NACE SP0207 | Performing Close-Interval Potential Surveys | CIS methodology and data interpretation |
| NACE SP0502 | Pipeline External Corrosion Direct Assessment (ECDA) | Integrates CIS data into ECDA process |
| NACE TM0497 | Measurement Techniques Related to Criteria for CP | IR drop compensation methods |
| 49 CFR 192 | Transportation of Natural Gas by Pipeline | Federal CP requirements for gas pipelines |
| 49 CFR 195 | Transportation of Hazardous Liquids by Pipeline | Federal CP requirements for liquid pipelines |
| NACE SP0286 | Electrical Isolation of CP Systems | Isolation joint design and testing |
| NACE SP0572 | Design and Installation of Offshore CP Systems | Marine and offshore CP applications |
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