Gas Processing & Quality

Wobbe Index & Gas Interchangeability

Understand the Wobbe Index as the primary criterion for fuel gas substitution and interchangeability. Learn AGA indices, burner design implications, gas quality tariff specifications, and hydrogen blending effects for pipeline and distribution systems.

Pipeline natural gas

WI 1,310–1,390

Btu/scf at 60°F, 14.696 psia. Typical US pipeline quality range.

Interchangeability band

±5% of target WI

Two gases within ±5% deliver equal heat through the same burner orifice.

Key standard

ISO 6976 / AGA No. 5

Calorific value calculation and natural gas interchangeability assessment.

Use this guide when you need to:

  • Assess whether two gases can substitute without burner modification.
  • Evaluate LNG cargo compatibility with receiving terminal specifications.
  • Determine hydrogen blending limits for pipeline gas.

1. What Is the Wobbe Index?

The Wobbe Index (WI) is the single most important parameter for assessing whether one fuel gas can replace another in combustion equipment without modification. Named after Italian engineer Goffredo Wobbe, it quantifies the thermal energy delivered through a fixed orifice at a given supply pressure, accounting for both heating value and gas density.

Definition

WI = HHV / √SG

Gross heating value divided by the square root of specific gravity (air = 1.0).

Physical meaning

Thermal input at constant pressure

Equal Wobbe Index means equal heat release through the same burner at the same gas pressure.

Net Wobbe Index

WInet = LHV / √SG

Uses lower heating value. Preferred in Europe (EN 437) and for gas turbine applications.

Modified Wobbe Index

MWI = HHV / √(SG × T/Tref)

Temperature-corrected. Critical for gas turbine fuel specifications where fuel gas temperature varies.

Why the Wobbe Index Matters

  • Gas substitution: Two gases with different compositions but the same Wobbe Index will deliver the same heat output through the same burner orifice at the same supply pressure, eliminating the need for equipment changes.
  • LNG trade: LNG cargoes from different sources (Qatar, Australia, US Gulf Coast) have different compositions. The Wobbe Index determines whether a cargo is compatible with a receiving terminal and its downstream consumers.
  • Pipeline blending: When streams with different compositions merge in a pipeline network, the resulting Wobbe Index must remain within the acceptable interchangeability band.
  • Gas quality tariffs: Pipeline operators specify allowable Wobbe Index ranges in their tariffs to protect downstream consumers and equipment.
  • Hydrogen blending: As hydrogen is blended into natural gas networks for decarbonization, the Wobbe Index helps determine maximum allowable H2 concentration.
Critical concept: A gas with a higher heating value does not necessarily have a higher Wobbe Index. A rich gas with high HHV also has a high specific gravity, which partially offsets the heating value in the Wobbe calculation. This is why the Wobbe Index, not HHV alone, is the correct measure of interchangeability.

Typical Wobbe Index Values

Gas Type HHV (Btu/scf) SG (air=1) WI (Btu/scf) Notes
Pure methane 1,010 0.554 1,357 Reference baseline
Lean pipeline gas (95% C1) 1,020 0.58 1,340 Typical US transmission
Rich pipeline gas (85% C1) 1,100 0.65 1,364 Gathering system gas
LNG – Qatar 1,110 0.64 1,388 High ethane content
LNG – US Gulf Coast 1,030 0.59 1,341 Lean, treated gas
LNG – Australia (NWS) 1,060 0.61 1,357 Moderate richness
10% H2 blend 940 0.51 1,316 Hydrogen-natural gas blend
20% H2 blend 870 0.44 1,311 Near lower interchangeability limit
Landfill gas (50% CH4) 505 0.85 548 Not interchangeable without upgrading
Pure propane 2,516 1.522 2,039 Different gas family entirely

2. Derivation & Physics

The Wobbe Index derives from the fundamental relationship between orifice flow, gas density, and thermal energy release. Understanding the derivation explains why this single parameter captures gas interchangeability so effectively.

Orifice Flow and Heat Release

Volumetric flow through an orifice: Q = Cd × A × √(2 × ΔP / ρ) Where: Q = Volumetric flow rate (scf/hr) Cd = Discharge coefficient (dimensionless) A = Orifice area (ft²) ΔP = Pressure drop across orifice (lbf/ft²) ρ = Gas density at supply conditions (lb/ft³) Since ρ = SG × ρair: Q = Cd × A × √(2 × ΔP / (SG × ρair)) Q = K × 1 / √SG Where K = Cd × A × √(2 × ΔP / ρair) is constant for fixed geometry and pressure.

Thermal Input Derivation

Heat release rate at burner: ˙Qthermal = Q × HHV Substituting the orifice equation: ˙Qthermal = K × (1 / √SG) × HHV ˙Qthermal = K × (HHV / √SG) ˙Qthermal = K × WI Therefore: For a fixed burner (K = constant), the heat release rate is directly proportional to the Wobbe Index. Two gases with the same WI deliver the same thermal input regardless of their individual HHV and SG values. This is the fundamental principle of gas interchangeability.

Modified Wobbe Index

The standard Wobbe Index assumes gas arrives at the reference temperature (60°F or 15°C). When gas temperature differs from the reference, density changes and flow through the orifice is affected. The Modified Wobbe Index corrects for this.

Modified Wobbe Index (MWI): MWI = HHV / √(SG × Tgas / Tref) Where: Tgas = Actual gas temperature (Rankine or Kelvin) Tref = Reference temperature (519.67°R = 60°F, or 288.15 K = 15°C) Physical reasoning: Gas density at actual temperature: ρ = ρref × (Tref / Tgas) Higher gas temperature → lower density → higher volume flow → more gas through orifice But energy per unit volume remains the same (HHV is per standard cubic foot) Implications: - At Tgas = Tref: MWI = WI (no correction needed) - At Tgas > Tref: MWI < WI (hot gas delivers less energy than WI alone suggests) - At Tgas < Tref: MWI > WI (cold gas delivers more energy) Gas turbine application: Gas turbines are highly sensitive to fuel Wobbe Index. Fuel gas may arrive at 50–400°F depending on fuel treatment and heating. Typical GT MWI specification: 40–55 MJ/m³ (or equivalent Btu/scf range).

Unit Systems

Parameter US Customary SI / ISO Conversion
Heating Value (HHV) Btu/scf MJ/m³ 1 Btu/scf = 0.03732 MJ/m³
Wobbe Index Btu/scf MJ/m³ 1 Btu/scf = 0.03732 MJ/m³
Reference Temperature 60°F (14.696 psia) 15°C (101.325 kPa) Volume correction factor applies
Specific Gravity Dimensionless (air=1) Dimensionless (air=1) Same value in both systems
Reference conditions matter: Heating values and Wobbe Index change with reference conditions. US standard (60°F, 14.696 psia) gives different numerical values than ISO standard (15°C, 101.325 kPa). Always verify which reference conditions are being used when comparing Wobbe values from different sources.

3. AGA Interchangeability Indices

While the Wobbe Index is the primary interchangeability criterion, it does not capture all combustion phenomena. The American Gas Association (AGA) developed additional indices to assess flame stability, flashback tendency, and incomplete combustion risk. These are defined in AGA Bulletin No. 36 and AGA Report No. 5.

The Three AGA Indices

IL — Lifting Index (Flame Stability)

IL (Lifting Index): Measures the tendency of the flame to lift off the burner port. Physical basis: - Flame is anchored to the burner port by a balance between gas velocity and flame speed. - If gas exits too fast relative to its flame speed, the flame lifts and may blow off. - If gas exits too slowly, the flame may flash back into the burner. IL relates to the heat release rate and flame speed of the substitute gas compared to the reference gas. Acceptable range: IL = 0.8 to 1.2 IL < 0.8 → Flame may lift or blow off (under-fired) IL = 1.0 → Same flame characteristics as reference gas IL > 1.2 → Flame may flash back or burn too close to port (over-fired) Factors that increase IL: - Higher Wobbe Index (more heat release per unit area) - Higher flame speed (H2, C2H6 have faster flames than CH4) Factors that decrease IL: - Higher inert content (N2, CO2 dilute flame) - Lower heating value

IF — Flashback Index

IF (Flashback Index): Measures the tendency of the flame to propagate back into the burner mixing chamber (flashback). Physical basis: - Flashback occurs when flame speed exceeds gas velocity at the burner port. - Higher flame speed gases (H2, C2H6) are more prone to flashback. - Lower density gases flow faster through the orifice, partially compensating. IF is driven primarily by the flame speed ratio between substitute and reference gas, with a density correction. Acceptable limit: IF < 1.2 IF < 1.0 → Lower flashback risk than reference gas IF = 1.0 → Same flashback characteristics IF > 1.2 → Increased flashback risk; burner modification may be needed Critical factor: Hydrogen has a laminar flame speed of ~312 cm/s vs. 40 cm/s for methane. Even small H2 additions significantly increase IF.

IY — Yellow Tip Index (Incomplete Combustion)

IY (Yellow Tip Index): Measures the tendency toward incomplete combustion and carbon (soot) formation, visible as yellow tipping of the flame. Physical basis: - Heavier hydrocarbons (C3+) require more air for complete combustion. - If air supply is insufficient, carbon particles form and glow yellow. - Residential burners are typically designed for lean gas (C1-dominant). IY relates to the stoichiometric air requirement and density of the substitute gas relative to the reference gas. Acceptable limit: IY < 0.8 IY < 0.6 → Clean combustion, well within limits IY = 0.8 → At threshold; yellow tips beginning to appear IY > 0.8 → Incomplete combustion likely; CO emissions increase Factors that increase IY: - Higher C3+ content (more air needed per unit volume) - Higher specific gravity - Higher HHV (more fuel energy, more air needed) Factors that decrease IY: - Lean gas (high C1, low C3+) - Higher inert content (reduces combustible fraction)

AGA Index Summary

Index What It Measures Acceptable Range Key Driver Failure Consequence
IL Flame stability / lifting 0.8 – 1.2 Heat release × flame speed Flame lifts off or blows out
IF Flashback tendency < 1.2 Flame speed / gas density Flame enters mixing chamber
IY Incomplete combustion < 0.8 Air requirement / fuel richness Yellow tips, CO, soot

Weaver Interchangeability Method

The Weaver method is an alternative approach that uses six indices to characterize gas interchangeability more completely. It was developed by E.R. Weaver at the National Bureau of Standards and is referenced in AGA literature alongside the primary IL/IF/IY indices.

  • JL (Lifting): Similar to IL; based on primary air entrainment and flame speed balance
  • JF (Flashback): Similar to IF; accounts for burner port geometry effects
  • JY (Yellow Tip): Similar to IY; includes secondary air availability
  • JH (Heating Value): Direct heat input comparison for appliance capacity
  • JI (Incomplete Combustion): CO production tendency under air-lean conditions
  • JS (Speed of Combustion): Flame propagation velocity impact on burner performance
Practical guidance: For most pipeline and distribution engineering purposes, the Wobbe Index combined with IL, IF, and IY provides sufficient assessment. The full Weaver method is primarily used in detailed appliance testing and certification programs.

4. Burner Design & Combustion

Understanding how burners interact with varying gas quality is essential for applying the Wobbe Index correctly. Different burner types have different sensitivities to gas composition changes.

Atmospheric Burners (Residential/Commercial)

  • Operation: Gas exits an orifice, entrains primary air by momentum (Venturi effect), and burns at port
  • Air supply: Typically 40–60% primary air, remainder from secondary air around flame
  • Wobbe sensitivity: High — fixed orifice, no automatic compensation
  • Interchangeability band: ±5% Wobbe Index recommended
  • Typical equipment: Residential furnaces, water heaters, cooking appliances, commercial boilers

Forced-Draft Burners (Industrial)

  • Operation: Combustion air supplied by fan; fuel injected through nozzle or lance
  • Air supply: Air-fuel ratio controlled by linkage, valve, or electronic control
  • Wobbe sensitivity: Moderate — air-fuel ratio adjustment provides some compensation
  • Interchangeability band: ±10% with ratio adjustment, ±5% without
  • Typical equipment: Process heaters, boilers, thermal oxidizers

Gas Turbines

  • Operation: Premixed or diffusion flame in combustion chamber; fuel through multiple nozzles
  • Fuel specification: Modified Wobbe Index is the primary control parameter
  • Wobbe sensitivity: Very high — affects combustion dynamics, emissions, and turbine life
  • Typical MWI spec: ±5% of design value (tight control required)
  • Concerns: Flame holding, combustion instability (dynamics), NOx/CO emissions, hot gas path temperature

Combustion Effects of Gas Quality Variation

Gas Quality Change Effect on WI Flame Behavior Operational Impact
Higher C3+ content WI increases slightly Longer, more luminous flame; yellow tips Increased CO, soot; flame impingement risk
Higher N2 content WI decreases Shorter flame; lifting tendency Reduced capacity; flame instability
Higher CO2 content WI decreases Cooler flame; lower stability Reduced capacity; flame-out risk
Higher H2 content WI decreases (moderate) Faster flame speed; shorter flame Flashback risk; higher NOx at high H2
Higher gas temperature MWI decreases Higher flow rate; richer mixture Capacity increase; possible over-firing
Lower gas pressure No WI change Lower flow; flame closer to port Reduced capacity; flashback at very low P

Flame Speed Considerations

Laminar flame speed at standard conditions (1 atm, 25°C): Component flame speeds (cm/s): - Methane (CH4): 40 cm/s - Ethane (C2H6): 43 cm/s - Propane (C3H8): 46 cm/s - n-Butane (C4H10): 45 cm/s - Hydrogen (H2): 312 cm/s - Carbon monoxide: 47 cm/s Key observation: Hydrogen flame speed is ~8x that of methane. This is why hydrogen blending significantly affects flashback index (IF) even at low concentrations. For a gas mixture, the effective flame speed is approximately: SL,mix = Σ(yi × SL,i) / Σ(yi) (combustible components only) This linear mixing rule is approximate. Actual flame speeds depend on mixture stoichiometry, temperature, pressure, and turbulence.
Design practice: Gas turbine OEMs (GE, Siemens, Solar, Rolls-Royce) specify fuel gas requirements in terms of Modified Wobbe Index, heating value range, and maximum H2 content. Always verify compliance with the specific OEM fuel specification before operating on non-standard gas compositions.

5. Gas Quality & Pipeline Tariffs

Pipeline operators and gas utilities specify allowable gas quality parameters in their tariffs to protect downstream equipment and consumers. The Wobbe Index is increasingly used alongside traditional compositional limits.

Typical US Pipeline Gas Quality Specifications

Parameter Typical US Pipeline Gulf Coast Northeast US LNG Feed
HHV (Btu/scf) 950 – 1,100 967 – 1,110 970 – 1,100 1,000 – 1,100
Wobbe Index (Btu/scf) 1,310 – 1,390 1,310 – 1,400 1,310 – 1,385 1,340 – 1,400
CO2 (mol%) ≤ 2.0 ≤ 2.0 ≤ 2.0 ≤ 0.05
N2 (mol%) ≤ 3.0 ≤ 3.0 ≤ 3.0 ≤ 1.0
Total Inerts (mol%) ≤ 4.0 ≤ 4.0 ≤ 4.0 ≤ 1.5
H2S (grains/100scf) ≤ 0.25 ≤ 0.25 ≤ 0.25 ≤ 0.25
O2 (mol%) ≤ 0.2 ≤ 0.2 ≤ 0.1 ≤ 0.01
Water Dewpoint (°F) ≤ −30 ≤ −30 ≤ −40 ≤ −150

European Gas Quality Standards

European gas quality is governed by EN 437 (gas appliance categories) and national standards. Europe uses the Net Wobbe Index (based on LHV) as the primary parameter.

Gas Family EN 437 Group Net Wobbe (MJ/m³) Gross Wobbe (MJ/m³) Typical Application
Group H (High) 2H 45.7 – 54.7 48.2 – 56.5 Natural gas (most of Europe)
Group L (Low) 2L 39.1 – 44.8 41.2 – 46.8 Low-cal gas (Netherlands, Belgium)
Group E (Extended) 2E 40.9 – 54.7 43.0 – 56.5 Harmonized European range (future)

LNG Cargo Assessment

LNG terminals must evaluate each cargo for compatibility with the downstream gas network. The Wobbe Index is the primary screening parameter.

LNG Cargo Acceptance Criteria: Step 1: Determine regasified LNG composition - From ship's GC analysis or bill of lading - Account for boil-off gas (BOG) composition change during voyage Step 2: Calculate Wobbe Index - WI = HHV / √SG at standard conditions (60°F, 14.696 psia) Step 3: Compare to terminal specification - Typical US LNG terminal: WI = 1,310 – 1,420 Btu/scf - If outside range: nitrogen ballasting or blending required Step 4: Mitigation options for off-spec LNG - Nitrogen injection: Reduces HHV and WI (1 mol% N2 ≈ −10 Btu/scf HHV) - Blending with pipeline gas: Dilutes rich LNG with leaner pipeline gas - LPG extraction: Removes C3+ to reduce HHV (used at some terminals) - Cargo rejection: Last resort if no mitigation feasible Example: Qatar LNG: HHV = 1,110 Btu/scf, SG = 0.64 WI = 1,110 / √0.64 = 1,388 Btu/scf US pipeline spec WI max: 1,390 Btu/scf Result: Marginally within spec. N2 ballasting may be needed for safety margin.

Gas Blending for Wobbe Adjustment

Blending Calculation (Volume Basis): For two gas streams A and B mixed: HHVmix = xA × HHVA + xB × HHVB SGmix = xA × SGA + xB × SGB Where xA + xB = 1.0 (volume fractions) WImix = HHVmix / √SGmix Note: WImix is NOT a linear blend of WIA and WIB because the square root function makes the relationship non-linear. To find blend ratio for target WI, solve iteratively: 1. Assume xA 2. Calculate HHVmix and SGmix 3. Calculate WImix 4. Adjust xA until WImix = WItarget Example: Stream A: Rich LNG, WI = 1,410 Btu/scf (HHV=1,120, SG=0.63) Stream B: Lean pipeline, WI = 1,330 Btu/scf (HHV=1,010, SG=0.58) Target: WI = 1,360 Btu/scf At xA = 0.40: HHVmix = 0.40 × 1,120 + 0.60 × 1,010 = 1,054 SGmix = 0.40 × 0.63 + 0.60 × 0.58 = 0.600 WImix = 1,054 / √0.600 = 1,361 Btu/scf (acceptable)
Tariff compliance: Pipeline operators may reject gas that does not meet Wobbe Index specifications. Producers and shippers must ensure their gas meets tariff requirements before delivery. Non-compliant gas may be subject to penalties, processing charges, or outright rejection at receipt points.

6. Hydrogen Blending Effects

Blending hydrogen into natural gas pipelines is a key strategy for decarbonizing energy systems. However, hydrogen has fundamentally different combustion properties than methane, and the Wobbe Index is an essential tool for determining safe blending limits.

Hydrogen vs. Methane Properties

Property Methane (CH4) Hydrogen (H2) Ratio H2/CH4 Impact
Molecular weight 16.04 2.016 0.126 Much lighter gas
HHV (Btu/scf) 1,010 324 0.321 1/3 the energy per scf
HHV (Btu/lb) 23,890 61,100 2.56 2.5x energy per unit mass
Specific gravity 0.554 0.070 0.126 Very low density
Wobbe Index (Btu/scf) 1,357 1,225 0.903 ~10% lower than CH4
Flame speed (cm/s) 40 312 7.8 8x faster flame
Adiabatic flame temp (°F) 3,542 3,807 1.07 Slightly hotter flame
Flammability range (vol%) 5 – 15 4 – 75 Much wider range

Wobbe Index at Various H2 Blending Levels

H2 blending effect on natural gas (base: 95% CH4, 3% C2, 2% N2): 0% H2: HHV = 1,023, SG = 0.586, WI = 1,336 Btu/scf (reference) 5% H2: HHV = 989, SG = 0.541, WI = 1,344 Btu/scf (+0.6%) 10% H2: HHV = 953, SG = 0.495, WI = 1,354 Btu/scf (+1.3%) 15% H2: HHV = 918, SG = 0.450, WI = 1,369 Btu/scf (+2.5%) 20% H2: HHV = 883, SG = 0.404, WI = 1,389 Btu/scf (+4.0%) 25% H2: HHV = 848, SG = 0.358, WI = 1,417 Btu/scf (+6.1%) 30% H2: HHV = 814, SG = 0.313, WI = 1,454 Btu/scf (+8.8%) Key observation: The Wobbe Index initially INCREASES with hydrogen blending (up to ~25%) because the density decrease (denominator) outweighs the heating value decrease (numerator). This is counterintuitive but physically correct. At very high H2 levels (>50%), WI starts to decrease: 50% H2: HHV = 667, SG = 0.177, WI = 1,585 Btu/scf 100% H2: HHV = 324, SG = 0.070, WI = 1,225 Btu/scf The non-monotonic behavior means WI alone is insufficient for assessing hydrogen blending safety. Flame speed indices (IF) and methane number must also be checked.

H2 Blending Limits by Application

Application / Equipment Max H2 (vol%) Limiting Factor Standard / Reference
Residential appliances (generic) 5 – 20% Flashback, flame detection ASME/CSA; varies by appliance age
Industrial burners (pre-mix) 5 – 15% Flashback at burner port Manufacturer specification
Gas turbines (DLN combustors) 5 – 15% Combustion dynamics, flashback OEM fuel spec (GE, Siemens)
Gas turbines (diffusion) 30 – 100% Materials, NOx emissions OEM fuel spec
Gas engines (lean-burn) 2 – 10% Knock / pre-ignition Methane number > 65
CNG vehicles 2 – 5% Tank embrittlement, seals ISO 15403, SAE J1616
Pipeline steel (X52–X70) 10 – 20% Hydrogen embrittlement ASME B31.12
Gas meters (diaphragm) 20 – 30% Measurement accuracy EN 1359, OIML R137

Methane Number and Gas Engines

Methane Number (MN): Definition: Knock resistance rating for gas engine fuel, analogous to octane number for gasoline. Scale from 0 (hydrogen) to 100 (pure methane). MN = 100: Pure methane (most knock-resistant) MN = 80: Typical pipeline gas (acceptable for most engines) MN = 65: Minimum for lean-burn gas engines (Caterpillar, Wartsila, Jenbacher) MN = 44: Ethane MN = 20: Propane MN = 0: Hydrogen (most knock-prone) Effect of H2 blending on MN: Each 1% H2 reduces MN by approximately 0.5–1.0 points. At 10% H2 in pipeline gas: MN drops from ~80 to ~70–75 At 20% H2: MN drops to ~60–65 (marginal for lean-burn engines) Gas engine derating: Below MN 80, many engines require derating (reduced power output) to prevent knocking. Typical derating: 1–2% power per MN point below 80.
Hydrogen blending challenge: The Wobbe Index suggests H2 blending up to 20–25% is acceptable from a thermal input perspective. However, the dramatically higher flame speed of hydrogen creates flashback and safety risks well before that level. In practice, 5–20% H2 is the typical limit for existing infrastructure, constrained by the weakest link in the gas chain (usually residential appliances or gas engines).

7. Industry Applications

The Wobbe Index finds application across the entire natural gas value chain, from upstream production through processing, transmission, distribution, and end use.

Upstream & Gathering Systems

  • Field gas characterization: Wobbe Index screening determines whether field gas needs processing before pipeline delivery. Gas with WI outside tariff limits requires treatment (NGL recovery, N2 rejection, CO2 removal).
  • Commingled production: When gas from multiple wells or formations is combined at a gathering facility, the blended Wobbe Index must remain within pipeline tariff specifications.
  • Fuel gas selection: On-site compressor and heater fuel gas must meet equipment specifications. Low-WI gas (high inerts) may not sustain stable combustion.

Gas Processing Plants

  • NGL recovery optimization: Deeper NGL recovery (more C3+ removal) lowers HHV but also lowers SG. The net effect on Wobbe Index depends on which changes more. Plant operators monitor WI to ensure residue gas meets tariff requirements.
  • Nitrogen rejection: N2 removal increases both HHV and SG (removing a light diluent), generally increasing WI. NRU product gas is typically richer than feed gas.
  • CO2 removal: Amine treating removes CO2, increasing HHV while reducing SG (CO2 is denser than methane). WI typically increases after treating.

Transmission Pipelines

  • Receipt point quality: Gas quality gates at pipeline receipt points verify incoming gas meets tariff WI specifications. Non-conforming gas is rejected or subject to penalties.
  • Blending at interconnects: Where pipelines interconnect, gases from different sources blend. Operators track WI at key points to ensure the blended gas remains within spec throughout the network.
  • Storage injection/withdrawal: Gas injected into storage may have different composition than gas withdrawn (due to mixing with cushion gas). WI monitoring ensures withdrawn gas meets pipeline specs.

LNG Value Chain

  • Feed gas specification: LNG plant feed gas must meet tight composition specs for cryogenic processing. WI is used for initial screening.
  • Cargo quality management: Each LNG cargo has a unique composition profile. WI determines whether the cargo is compatible with the destination terminal and downstream market.
  • Regasification terminal: Terminals may need nitrogen ballasting to reduce WI for rich LNG cargoes, or LPG extraction for very rich cargoes.
  • Market compatibility: Different markets (US, Europe, Asia) have different WI specifications. A cargo acceptable in one market may not be acceptable in another without treatment.

Distribution & End Use

  • City gate stations: Gas distribution companies monitor WI at city gate stations to ensure gas delivered to residential and commercial customers is within appliance design specifications.
  • Appliance certification: Gas appliances are tested and certified for specific gas families defined by Wobbe Index ranges (EN 437 gas groups). Operating outside these ranges voids certification.
  • Gas blending stations: Some utilities operate blending stations where propane-air or LNG is blended with pipeline gas to manage WI during peak demand or supply disruptions.

Renewable and Synthetic Gas

  • Biomethane (RNG): Upgraded biogas (95%+ CH4) typically has WI close to pipeline gas and is interchangeable without issues. Raw biogas (50–60% CH4, 40–50% CO2) has a very low WI and is not pipeline-compatible.
  • Synthetic natural gas (SNG): Methanation of hydrogen and CO2 produces SNG with WI similar to pipeline gas. Quality depends on conversion efficiency and residual H2/CO2.
  • Power-to-gas: Electrolytic hydrogen blended into gas networks. WI is used alongside flame speed indices to determine maximum injection rates per the discussion in Section 6.

Measurement and Monitoring

Real-time gas quality analysis: Online instruments for WI monitoring: - Gas chromatograph (GC): Full composition analysis, WI calculated - Cycle time: 3–10 minutes - Accuracy: ±0.1% on composition, ±1 Btu/scf on HHV - Calorimeter (direct measurement): - Cutler-Hammer or Therm-O-Flow type - Measures HHV directly by combustion - Requires separate SG measurement for WI - Correlative sensors (speed of sound, infrared): - Faster response (seconds vs. minutes) - Lower accuracy (±5–10 Btu/scf on HHV) - Useful for trending and alarm purposes - Portable analyzers: - FTIR or laser-based for spot checks - Suitable for field verification Monitoring frequency: - Pipeline receipt points: Continuous GC analysis (every 5–10 min) - City gate stations: Hourly or continuous - Industrial fuel gas: Continuous for gas turbines, periodic for boilers - LNG terminals: Per-cargo analysis + continuous blend monitoring

Best Practices Summary

  • Always check WI, not just HHV: Two gases with the same HHV can have different Wobbe Indices if their specific gravities differ. WI is the correct interchangeability criterion.
  • Use all three AGA indices: The Wobbe Index addresses heat input but not flame stability, flashback, or soot formation. Check IL, IF, and IY for complete assessment.
  • Specify reference conditions: Always state whether WI is at 60°F/14.696 psia (US) or 15°C/101.325 kPa (ISO). Numerical values differ between systems.
  • Account for temperature: Use Modified Wobbe Index for gas turbine applications and when gas temperature differs significantly from the reference.
  • Design for the weakest link: The maximum allowable Wobbe Index variation is determined by the most sensitive equipment in the gas chain (typically residential appliances or lean-burn gas engines).
  • Monitor continuously: Gas composition can change due to upstream processing changes, well workovers, storage cycling, or LNG cargo switches. Continuous WI monitoring prevents off-spec gas from reaching sensitive consumers.