EPA AP-42 Ch. 7.1 for Fixed-Roof, IFR, and EFR Tanks
AP-42 equations, vapor space expansion factor, RVP-to-TVP conversion, OOOO applicability, control device payback.
Standing (breathing) loss:
Working loss:
Vapor density:
Vapor space saturation factor:
Turnover factor:
Product factor KP: crude = 1.00; refined = 0.75.
R = 10.731 psia·ft³/(lbmol·°R).
EPA's compendium of emission-factor equations for organic liquid storage tanks (fixed-roof, IFR, EFR). Output feeds Title V PTE and NSPS Kb / OOOOa/b/c applicability.
Working = vapor displaced by added liquid (scales with throughput). Breathing = vapor pushed out by daily T and P swings (scales with vapor-space volume and ΔT). Total = sum.
Single-tank uncontrolled VOC > 6 ton/yr → OOOOa/b/c controls required (95% capture, typically VRU + flare, monthly inspections).