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Debutanizer (DeC4) Sizing Calculator

GPSA Ch. 16 / GPA 2140

Debutanizer (DeC4) Sizing Calculator
Sizes debutanizer fractionation columns using the Fenske-Underwood-Gilliland shortcut method. Separates C₄ (butanes) from C₅+ (natural gasoline/pentanes+) to produce mixed butane product and natural gasoline. Calculates minimum stages, minimum reflux ratio, actual trays, column diameter, and reboiler/condenser duties per GPSA Ch. 16 and GPA 2140.
GPSA Ch. 16 GPA 2140
Calculation Mode:
Design: Size debutanizer from feed composition and product specifications.

Feed Conditions

BPD
°F
psig

Feed Composition (mol%)

Trace from depropanizer

Product Specifications

mol%
mol%

Column Design Parameters

%
in
%

Typical Debutanizer Operating Conditions

Parameter Range
Pressure75–150 psig
Overhead Temp120–160°F
Bottoms Temp300–400°F
Reflux Ratio1.0–2.5
Trays25–40

Engineering Basis

Fenske Equation (Minimum Stages):

Nmin = ln[(xLK,D / xHK,D)(xHK,B / xLK,B)] / ln(α)

Where xLK,D = light key (nC₄) mole fraction in distillate, xHK,B = heavy key (iC₅) mole fraction in bottoms, α = average relative volatility of nC₄ to iC₅.

Gilliland Correlation:

(N − Nmin) / (N + 1) = f[(R − Rmin) / (R + 1)]

Correlates actual stages N to actual reflux ratio R given minimum stages Nmin and minimum reflux Rmin from the Underwood equation.

Underwood Equation: Determines minimum reflux ratio Rmin from feed composition, feed condition (q), and relative volatilities. Combined with Gilliland correlation to find actual stages at the design reflux multiplier.

Column Diameter: Sized from vapor/liquid traffic using Fair’s flooding correlation at the design flood fraction.

Design Guidelines

Operating Pressure: Debutanizers typically operate at 75–150 psig, lower than depropanizers, as the heavier C₄/C₅ separation allows condensation at lower pressures.
Natural Gasoline: Bottoms product (C₅+) is natural gasoline used for gasoline blending, petrochemical feedstock, or diluent.
Condenser Type: Total condensers produce liquid mixed-butane product. Air-cooled condensers are typical at these overhead temperatures.

Frequently Asked Questions

What is a debutanizer column and what does it separate?

A debutanizer (DeC4) is a fractionation column that separates C₄ (butanes) from C₅+ (natural gasoline/pentanes+). It produces mixed butane product overhead and natural gasoline as bottoms product.

What method does this debutanizer sizing calculator use?

This calculator uses the Fenske-Underwood-Gilliland (FUG) shortcut method per GPSA Ch. 16 and GPA 2140. It calculates minimum stages, minimum reflux ratio, actual trays, column diameter, and reboiler/condenser duties.

What are typical debutanizer operating conditions?

Typical debutanizer conditions include 75–150 psig pressure, 120–160°F overhead temperature, 300–400°F bottoms temperature, reflux ratio of 1.0–2.5, and 25–40 trays.

What are the key components (light key and heavy key) in a debutanizer?

In a debutanizer, the light key is n-butane (nC₄) and the heavy key is iso-pentane (iC₅). The separation is based on the relative volatility between these two components.