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Debutanizer (DeC4) Sizing Calculator

Size a debutanizer column with the Fenske-Underwood-Gilliland method: stages, reflux, and duty.

GPSAGPA 2140
Debutanizer (DeC4) Sizing Calculator
Sizes debutanizer fractionation columns using the Fenske-Underwood-Gilliland shortcut method. Separates C₄ (butanes) from C₅+ (natural gasoline/pentanes+) to produce mixed butane product and natural gasoline. Calculates minimum stages, minimum reflux ratio, actual trays, column diameter, and reboiler/condenser duties per GPSA §19 and GPA 2140.
GPSA §19 GPA 2140
Calculation Mode:
Design: Size debutanizer from feed composition and product specifications.

Feed Conditions

BPD
°F
psig

Feed Composition (mol%)

Trace from depropanizer

Product Specifications

mol%
mol%

Column Design Parameters

%
in
%

Relative Volatility Basis

No general correlation reproduces GPSA convergence‑pressure chart K‑values across the full pressure range. All three methods are reported with every result so the spread is visible. For detailed design, enter α from a process simulator, GPSA Section 25 charts, or plant data — that overrides the correlation entirely.

Typical Debutanizer Operating Conditions

Parameter Range
Pressure75–150 psig
Overhead Temp120–160°F
Bottoms Temp300–400°F
Reflux Ratio1.0–2.5
Trays25–40

Engineering Basis

Fenske Equation (Minimum Stages):

Nmin = ln[(xLK,D / xHK,D)(xHK,B / xLK,B)] / ln(α)

Where xLK,D = light key (nC₄) mole fraction in distillate, xHK,B = heavy key (iC₅) mole fraction in bottoms, α = average relative volatility of nC₄ to iC₅.

Gilliland Correlation:

(N − Nmin) / (N + 1) = f[(R − Rmin) / (R + 1)]

Correlates actual stages N to actual reflux ratio R given minimum stages Nmin and minimum reflux Rmin from the Underwood equation.

Underwood Equation: Determines minimum reflux ratio Rmin from feed composition, feed condition (q), and relative volatilities. Combined with Gilliland correlation to find actual stages at the design reflux multiplier.

Column Diameter: Sized from vapor/liquid traffic using Fair’s flooding correlation at the design flood fraction.

Design Guidelines

Operating Pressure: Debutanizers typically operate at 75–150 psig, lower than depropanizers, as the heavier C₄/C₅ separation allows condensation at lower pressures.
Natural Gasoline: Bottoms product (C₅+) is natural gasoline used for gasoline blending, petrochemical feedstock, or diluent.
Condenser Type: Total condensers produce liquid mixed-butane product. Air-cooled condensers are typical at these overhead temperatures.

Frequently Asked Questions

What is a debutanizer column and what does it separate?

A debutanizer (DeC4) is a fractionation column that separates C₄ (butanes) from C₅+ (natural gasoline/pentanes+). It produces mixed butane product overhead and natural gasoline as bottoms product.

What method does this debutanizer sizing calculator use?

This calculator uses the Fenske-Underwood-Gilliland (FUG) shortcut method per GPSA §19 and GPA 2140. It calculates minimum stages, minimum reflux ratio, actual trays, column diameter, and reboiler/condenser duties.

What are typical debutanizer operating conditions?

Typical debutanizer conditions include 75–150 psig pressure, 120–160°F overhead temperature, 300–400°F bottoms temperature, reflux ratio of 1.0–2.5, and 25–40 trays.

What are the key components (light key and heavy key) in a debutanizer?

In a debutanizer, the light key is n-butane (nC₄) and the heavy key is iso-pentane (iC₅). The separation is based on the relative volatility between these two components.