Safety & Risk Assessment

Gas Leak Rate Calculations

Calculate gas leak rates through orifices and pipeline ruptures, distinguish choked vs unchoked flow regimes, apply API 581 hole size categories, and perform dispersion modeling for emergency response planning.

Choked flow threshold

P_d/P_u < 0.528

Flow becomes sonic (choked) when downstream/upstream pressure ratio < 0.528 for ideal gas.

API 581 small leak

6.35 mm (1/4")

Small hole: 6.35 mm diameter; used for risk-based inspection analysis.

Typical 4" rupture

100-400 lb/s gas

Full-bore rupture of 4-inch gas line at 800 psi releases 100-400 lb/s depending on gas properties and Cd.

Use this guide when you need to:

  • Calculate gas release rates for safety studies.
  • Size emergency shutdown (ESD) systems.
  • Perform quantitative risk assessment (QRA) per API 581.

1. Overview & Applications

Gas leak rate calculations are fundamental to process safety management, risk-based inspection (RBI), emergency response planning, and regulatory compliance. Accurate leak rate prediction enables proper sizing of safety systems, evaluation of hazard zones, and prioritization of integrity management activities.

Quantitative risk assessment

QRA & RBI (API 581)

Consequence modeling requires leak rates for small, medium, large, and rupture scenarios.

Emergency shutdown sizing

ESD valve capacity

ESD systems must isolate inventory faster than critical leak rates.

Dispersion modeling

Flammable cloud extent

PHAST, ALOHA, or CFD models require source leak rate as primary input.

Regulatory compliance

EPA RMP & OSHA PSM

Risk Management Plans require worst-case and alternative release scenarios.

Key Concepts

  • Choked flow: Sonic velocity at orifice; mass flow rate independent of downstream pressure
  • Unchoked (subsonic) flow: Mass flow depends on pressure differential across orifice
  • Critical pressure ratio: P_d/P_u threshold below which flow becomes choked (~0.528 for ideal gas, k=1.4)
  • Discharge coefficient (Cd): Accounts for real orifice geometry vs idealized sharp-edged hole (typically 0.6-1.0)
  • Blowdown time: Duration to depressurize vessel or pipe segment after isolation
Why leak rates matter: A 1-inch diameter hole in a 600 psig natural gas pipeline releases approximately 5-8 lb/s (400-600 Mscf/hr) depending on hole geometry. Within 60 seconds, this forms a flammable vapor cloud exceeding 100,000 ft³ at lower flammable limit (LFL). Accurate leak rate prediction is essential for determining safe separation distances and emergency response times.
Gas leak consequence progression diagram showing timeline from initial release through vapor cloud formation, atmospheric dispersion, ignition decision point branching to either fire and explosion consequences or safe dispersion below LFL
Gas leak consequence progression from initial release through vapor cloud formation to potential fire/explosion or safe dispersion outcomes

2. Orifice Leak Rate Equations

Gas flow through an orifice (leak, hole, or rupture) is governed by compressible flow equations. The mass flow rate depends on upstream pressure, temperature, gas properties, hole size, and whether flow is choked or unchoked.

General Orifice Flow Equation

Mass Flow Rate Through Orifice: ṁ = Cd × A × ρ × V Where: ṁ = Mass flow rate (lb/s or kg/s) Cd = Discharge coefficient (dimensionless, typically 0.6-1.0) A = Orifice area (ft² or m²) ρ = Gas density upstream (lb/ft³ or kg/m³) V = Gas velocity through orifice (ft/s or m/s) For compressible flow, velocity and density are coupled through thermodynamics.

Choked Flow (Sonic) Equation

Choked Flow (P_d/P_u ≤ Critical Ratio): The isentropic choked mass flow rate through an orifice: ṁ = Cd × A × P₁ × √(g_c × MW / (R_mech × T₁ × Z₁)) × C Where C = √[ k × (2/(k+1))^((k+1)/(k-1)) ] (choked flow constant) In practical US customary units (A in in², P in psia, T in °R): ṁ (lb/s) = Cd × A (in²) × P₁ (psia) × 0.1443 × C × √(MW / (T₁(°R) × Z₁)) The combined coefficient (0.1443 × C) varies with k: k = 1.27 (natural gas): 0.1443 × 0.662 = 0.0955 k = 1.30 (methane): 0.1443 × 0.667 = 0.0963 k = 1.40 (air): 0.1443 × 0.685 = 0.0988 Where: 0.1443 = √(g_c / R_mech) = √(32.174 / 1545.35) g_c = 32.174 lbm·ft/(lbf·s²) (gravitational conversion constant) R_mech = 1545.35 ft·lbf/(lbmol·°R) (universal gas constant) k = Specific heat ratio (Cp/Cv, typically 1.27-1.40 for natural gas) MW = Molecular weight (lb/lbmol) T₁ = Upstream temperature (°R = °F + 459.67) Z₁ = Compressibility factor at upstream conditions P₁ = Upstream absolute pressure (psia) Critical pressure ratio (choked flow threshold): P_crit/P₁ = (2/(k+1))^(k/(k-1)) For k = 1.4: P_crit/P₁ = 0.528 If P_downstream < 0.528 × P_upstream, flow is choked.

Unchoked Flow (Subsonic) Equation

Unchoked Flow (P_d/P_u > Critical Ratio): ṁ = Cd × A × P₁ × 0.1443 × √[(2k/(k-1)) × (MW/(T₁×Z₁)) × ((P₂/P₁)^(2/k) - (P₂/P₁)^((k+1)/k))] Where: P₂ = Downstream absolute pressure (psia) 0.1443 = √(g_c / R_mech) (same constant as choked equation) The expansion term [(P₂/P₁)^(2/k) - (P₂/P₁)^((k+1)/k)] replaces the choked flow constant C, and captures the pressure-ratio dependence. For small pressure drops (P₂/P₁ > 0.8), unchoked flow can be approximated: ṁ ≈ Cd × A × √(2 × ρ₁ × ΔP) (incompressible approximation)

Worked Example: Choked Flow

Calculate mass flow rate through a 1-inch diameter hole in a natural gas pipeline at 800 psig, 80°F:

Given: Hole diameter d = 1.0 inch Upstream pressure P₁ = 800 + 14.7 = 814.7 psia Upstream temperature T₁ = 80 + 459.67 = 539.67 °R Gas properties: MW = 18.0, k = 1.27, Z₁ = 0.92 Discharge coefficient Cd = 0.85 (rounded/short-tube hole) Downstream pressure P₂ = 14.7 psia (atmospheric) Step 1: Check if flow is choked Critical ratio = (2/(k+1))^(k/(k-1)) For k = 1.27: Critical ratio = (2/2.27)^(1.27/0.27) = 0.551 P₂/P₁ = 14.7 / 814.7 = 0.018 << 0.551 Flow IS choked (sonic at orifice throat). Step 2: Calculate orifice area A = π × d² / 4 = π × 1.0² / 4 = 0.785 in² Step 3: Calculate choked flow constant C C = √[ k × (2/(k+1))^((k+1)/(k-1)) ] C = √[ 1.27 × (2/2.27)^(2.27/0.27) ] C = √[ 1.27 × 0.345 ] = √0.438 = 0.662 Combined coefficient = 0.1443 × 0.662 = 0.0955 Step 4: Apply choked flow equation ṁ = Cd × A × P₁ × 0.0955 × √(MW / (T₁ × Z₁)) ṁ = 0.85 × 0.785 × 814.7 × 0.0955 × √(18.0 / (539.67 × 0.92)) ṁ = 0.85 × 0.785 × 814.7 × 0.0955 × √(0.0363) ṁ = 0.85 × 0.785 × 814.7 × 0.0955 × 0.1904 ṁ = 9.89 lb/s Step 5: Convert to volumetric flow at standard conditions For 1 lbmol ideal gas at 14.7 psia, 60°F: V = 379.5 scf/lbmol Mass per mole = 18.0 lb/lbmol scf/hr = (9.89 lb/s × 3600 s/hr) / (18.0 lb/lbmol) × 379.5 scf/lbmol scf/hr = 750,600 scf/hr = 750.6 Mscf/hr = 18,014 Mscfd Result: A 1-inch hole at 800 psig releases 9.9 lb/s or 18,000 Mscfd of natural gas. In 1 minute: 593 lb or 12,500 scf released In 10 minutes: 5,934 lb or 125,100 scf released Note: This is the instantaneous rate at full upstream pressure. In practice, pipeline pressure decays after isolation, reducing the leak rate over time.

Discharge Coefficient (Cd) Values

Orifice Type Typical Cd Description
Sharp-edged circular hole 0.60-0.65 Corrosion pit, drilled hole, puncture
Well-rounded nozzle 0.95-1.00 Machined opening, flange connection
Short pipe (L/d = 2-3) 0.80-0.85 Crack with depth, weld defect
Long pipe (L/d > 10) 0.70-0.75 Through-wall crack, corroded pathway
Rupture (guillotine break) 1.00 Full-bore pipe rupture (no orifice restriction)
Safety valve discharge 0.975 (per ASME) Certified relief valve orifice

Conservative practice: For leak rate safety studies, use Cd = 1.0 to predict maximum (worst-case) release rate. For realistic consequence modeling, use Cd = 0.6-0.85 based on expected hole morphology.

Orifice flow schematic cross-section showing high pressure gas with upstream conditions P1, T1, rho flowing through hole diameter d, vena contracta at maximum velocity, jet expansion downstream, with mass flow rate equation and discharge coefficient reference values
Orifice flow through pipe wall showing upstream conditions, vena contracta formation, and downstream jet expansion with discharge coefficient reference

3. Choked vs Unchoked Flow Regimes

Understanding whether gas flow is choked (sonic) or unchoked (subsonic) is critical for accurate leak rate prediction. Choked flow is independent of downstream pressure, simplifying calculations for atmospheric releases.

Flow Regime Determination

Critical Pressure Ratio as Function of k: P_crit / P_upstream = (2 / (k+1))^(k/(k-1)) k value Critical ratio Application 1.40 0.528 Air, nitrogen, oxygen 1.30 0.546 Methane (approx) 1.27 0.551 Natural gas (typical) 1.20 0.565 Ethane, heavier gases 1.10 0.585 CO₂, refrigerants Decision rule: IF (P_downstream / P_upstream) < Critical_ratio THEN Flow is CHOKED (use choked equation) ELSE Flow is UNCHOKED (use subsonic equation) END IF Example: Natural gas (k = 1.27) at 600 psig = 614.7 psia Discharging to atmosphere (14.7 psia) P_d / P_u = 14.7 / 614.7 = 0.024 < 0.551 → CHOKED Same gas discharging to downstream vessel at 400 psia: P_d / P_u = 400 / 614.7 = 0.651 > 0.551 → UNCHOKED

Velocity at Choked Conditions

Sonic Velocity (Speed of Sound in Gas): a = √(k × R × T / MW) In US units: a (ft/s) = 223.0 × √(k × T(°R) / MW) Where 223.0 = √(g_c × R_mech) = √(32.174 × 1545.35) For natural gas (MW = 18, k = 1.27) at 80°F (540°R): a = 223.0 × √(1.27 × 540 / 18) a = 223.0 × √(38.1) a = 223.0 × 6.17 a = 1,376 ft/s = 939 mph This is the maximum exit velocity for choked flow. Density and velocity at throat (choked conditions): At sonic throat, Mach number M = 1.0 ρ_throat = ρ_upstream × (2/(k+1))^(1/(k-1)) V_throat = a (speed of sound) For k = 1.27: ρ_throat = 0.626 × ρ_upstream Significant density reduction due to isentropic expansion.

Effect of Downstream Pressure on Flow Rate

For unchoked flow, mass flow rate increases as pressure differential increases:

P_d/P_u Ratio Flow Regime ṁ / ṁ_choked Notes
1.00 No flow 0% No pressure differential
0.90 Unchoked ~30% Small ΔP, low flow
0.75 Unchoked ~60% Moderate ΔP
0.60 Near choked ~90% Approaching sonic conditions
0.528 (k=1.4) Critical 100% Transition to choked flow
< 0.528 Choked 100% Flow rate independent of P_d
Flow rate versus pressure ratio chart showing choked (sonic) flow region at constant 100% flow for P2/P1 below 0.528, transitioning to unchoked (subsonic) region where flow rate decreases as pressure ratio approaches 1.0, with critical ratio values for different k values
Normalized flow rate versus pressure ratio showing transition between choked and unchoked flow regimes at critical pressure ratio

Practical Implications for Safety Studies

  • Atmospheric releases: Nearly all high-pressure gas releases to atmosphere are choked (P_u > 30 psia typically); use choked equation
  • Releases into confined spaces: Downstream pressure can build up, potentially transitioning from choked to unchoked; requires dynamic modeling
  • Isolation valve closure: As upstream pressure decays after isolation, flow may transition from choked to unchoked before stopping
  • Conservative assumption: Always assume choked flow for maximum leak rate unless proven otherwise by pressure ratio calculation

Blowdown Time Estimation

Vessel Blowdown Through Orifice (Choked Flow): For isothermal blowdown (constant temperature assumption), the choked flow rate is proportional to pressure: ṁ(P) ∝ P. This gives exponential pressure decay: dP/dt = −λ × P → P(t) = P₁ × e^(−λt) Where λ = Cd × A_ft² × 0.1443 × C × √(MW/(T×Z)) × R_mech × T × Z / (V × MW) Solving for time to reach P₂: t = (1/λ) × ln(P₁ / P₂) Example: 1000 ft³ vessel at 500 psia, 1-inch orifice, blow to 50 psia A = π × (1/12)² / 4 = 0.00545 ft² C = √[1.27 × (2/2.27)^(2.27/0.27)] = 0.662 Cd = 0.85, MW = 18.0, T = 540 °R, Z = 0.92 λ = 0.85 × 0.00545 × 0.1443 × 0.662 × √(18/(540×0.92)) × 1545.35 × 540 × 0.92 / (1000 × 18) λ = 0.003594 /s t = (1/0.003594) × ln(500/50) t = 278.3 × 2.303 t = 641 seconds ≈ 10.7 minutes Key insight: Even a 1-inch orifice can depressurize a 1000 ft³ vessel from 500 to 50 psia in about 11 minutes. However, for a long pipeline segment (miles of pipe with much larger volume), blowdown through a small leak can take hours. For emergency depressuring, API 521 recommends sizing depressuring valves to reduce pressure to 50% within 15 minutes (fire case).

4. API 581 Hole Size Categories

API Recommended Practice 581 (Risk-Based Inspection Methodology) defines four standardized hole size categories for consequence analysis. These categories represent small leaks, medium leaks, large leaks, and full-bore ruptures, each with different safety and environmental consequences.

API 581 hole size categories showing four scaled circles for Small (6.35mm, 1/4 inch), Medium (25.4mm, 1 inch), Large (101.6mm, 4 inch), and Rupture (full bore 12 inch example) with area ratios, leak rates, detection times, hazard zones, and flame length indicators
API 581 standardized hole size categories for risk-based inspection consequence analysis with relative scale comparison and consequence indicators

API 581 Hole Size Definitions

Category Hole Diameter Typical Causes Detection
Small 6.35 mm (0.25 inch, 1/4") Pinhole corrosion, small crack, threaded connection leak Often undetected for hours/days; may be found by gas detector or inspection
Medium 25.4 mm (1.0 inch) Larger corrosion hole, weld defect, flange gasket blowout Audible hissing, pressure drop, gas detectors alarm within minutes
Large 101.6 mm (4.0 inches) Partial pipe rupture, major corrosion failure, impact damage Immediate loud noise, rapid pressure loss, visible gas cloud
Rupture Full pipe diameter Guillotine break, seismic damage, external impact, severe corrosion Catastrophic; immediate loss of containment, loud roar, large vapor cloud

Leak Rate Calculations for API 581 Scenarios

Calculate instantaneous leak rates for a 12-inch natural gas pipeline at 900 psig, 70°F:

Pipeline conditions: Diameter = 12 inches (12.75" OD, 0.375" wall, 12.0" ID) Pressure P₁ = 900 + 14.7 = 914.7 psia Temperature T₁ = 70 + 459.67 = 529.67 °R Gas: MW = 17.5, k = 1.28, Z = 0.89 Cd = 0.85 (conservative for all scenarios) All flows are choked (P₂ = 14.7 psia, P₂/P₁ = 0.016 << 0.55) C = √[1.28 × (2/2.28)^(2.28/0.28)] = 0.664 Combined coefficient = 0.1443 × 0.664 = 0.0958 Use: ṁ = Cd × A × P₁ × 0.0958 × √(MW / (T₁ × Z₁)) Constant = 0.85 × 914.7 × 0.0958 × √(17.5 / (529.67 × 0.89)) = 74.51 × 0.1927 = 14.35 Small hole (d = 0.25 inch = 6.35 mm): A = π × 0.25² / 4 = 0.0491 in² ṁ = 14.35 × 0.0491 = 0.70 lb/s = 2,535 lb/hr Standard volume = 2,535 / 17.5 × 379.5 = 54,970 scf/hr = 1,319 Mscfd Medium hole (d = 1.0 inch = 25.4 mm): A = π × 1.0² / 4 = 0.785 in² ṁ = 14.35 × 0.785 = 11.3 lb/s = 40,560 lb/hr Volume = 40,560 / 17.5 × 379.5 = 879,600 scf/hr = 21,110 Mscfd = 21.1 MMscfd Large hole (d = 4.0 inches = 101.6 mm): A = π × 4.0² / 4 = 12.57 in² ṁ = 14.35 × 12.57 = 180.3 lb/s = 649,000 lb/hr Volume = 649,000 / 17.5 × 379.5 = 14,073,000 scf/hr = 337.8 MMscfd Rupture (d = 12.0 inches = 304.8 mm): A = π × 12.0² / 4 = 113.1 in² ṁ = 14.35 × 113.1 = 1,622 lb/s = 5,841,000 lb/hr Volume = 5,841,000 / 17.5 × 379.5 = 126,660,000 scf/hr = 3,040 MMscfd Summary (instantaneous rates at full upstream pressure): Small: 0.70 lb/s = 1,319 Mscfd Medium: 11.3 lb/s = 21,110 Mscfd (16× small) Large: 180 lb/s = 337,800 Mscfd (16× medium, 256× small) Rupture: 1,622 lb/s = 3,040,000 Mscfd (9× large, 2,300× small) Note: These are peak instantaneous rates. Actual sustained release rates decrease as pipeline pressure decays after isolation. For consequence modeling, time-varying release profiles or time-averaged rates are typically used.

Consequence Analysis per Hole Size

Hole Category Flammable Cloud (LFL) Toxic Impact Fire Consequences
Small (1/4") 50-200 ft radius (continuous) Localized (for H₂S or toxic gas) Jet flame 10-30 ft; minor fire
Medium (1") 200-500 ft radius Moderate area (< 100m radius) Jet flame 50-150 ft; equipment damage
Large (4") 500-1,500 ft radius Large area (100-300m radius) Jet flame 200-400 ft; major fire, thermal radiation hazard
Rupture (full bore) 1,000-3,000 ft radius Very large area (> 300m) Fireball or large jet flame; severe damage, fatalities likely

Frequency Assumptions (API 581 Generic)

API 581 provides generic failure frequencies for uninspected equipment:

Typical failure frequencies (events per year per pipe segment): Small hole: 1 × 10⁻⁴ to 1 × 10⁻³ (1 in 10,000 to 1 in 1,000 per year) Medium hole: 1 × 10⁻⁵ to 1 × 10⁻⁴ (1 in 100,000 to 1 in 10,000 per year) Large hole: 1 × 10⁻⁶ to 1 × 10⁻⁵ (1 in 1,000,000 to 1 in 100,000 per year) Rupture: 1 × 10⁻⁷ to 1 × 10⁻⁶ (1 in 10,000,000 to 1 in 1,000,000 per year) These are modified by: - Corrosion rate and inspection effectiveness - Mechanical damage susceptibility - Equipment complexity - Management system quality - Prior inspection findings Risk calculation: Risk = Frequency × Consequence For medium hole scenario: Frequency = 5 × 10⁻⁵ per year Consequence = $500,000 (property damage + business interruption) Risk = 5 × 10⁻⁵ × $500,000 = $25/year expected loss Aggregate across all scenarios for total risk per equipment item.

5. Gas Dispersion Modeling & Emergency Response

Leak rate calculations provide the source term for gas dispersion modeling, which predicts downwind concentrations, flammable cloud extent, and toxic exposure zones. This information is critical for emergency planning, facility siting, and public safety.

Gas dispersion plume plan view showing leak source with downwind concentration contours including UFL (15%) too rich to burn zone, flammable range between LFL and UFL, LFL (5%) boundary, and safe zone below LFL, with emergency response zones for immediate danger, evacuation, and shelter-in-place areas
Gas dispersion plume plan view with concentration contours and emergency response zone delineation based on Gaussian dispersion model

Dispersion Modeling Overview

Gaussian plume models

ALOHA, DEGADIS

Simple steady-state plume models for neutral or buoyant gases; regulatory screening.

Dense gas models

PHAST, SLAB

For heavier-than-air gases (propane, CO₂); accounts for gravity slumping.

CFD modeling

FLACS, ANSYS Fluent

High-fidelity 3D models for complex geometry, congestion, and explosion overpressure.

Jet release

PHAST jet model

High-momentum jets from pressurized releases; entrainment and mixing.

Key Dispersion Parameters

Source Term (from leak rate calculation): Mass flow rate: ṁ (lb/s or kg/s) Release height: H (m, typically 0-10m for pipeline) Exit velocity: V_exit (m/s, from choked or unchoked calculation) Exit temperature: T_exit (K, often cooler due to Joule-Thomson expansion) Atmospheric conditions: Wind speed: u (m/s, at 10m height) Atmospheric stability class: A-F (Pasquill-Gifford) A, B = Unstable (daytime, strong solar, good mixing) D = Neutral (overcast or transition) E, F = Stable (nighttime, calm, poor mixing - worst case) Temperature: T_amb (K) Relative humidity: RH% Gas properties: Molecular weight: MW Lower flammable limit: LFL (vol%, e.g., 5% for methane) Upper flammable limit: UFL (vol%, e.g., 15% for methane) Toxic limit: IDLH, ERPG-2, etc. (ppm) Output from dispersion model: Concentration C(x,y,z,t) as function of position and time Distance to LFL (flammable cloud extent) Distance to toxic threshold (IDLH, ERPG-2) Affected population count (if site-specific census data available)

Flammable Cloud Footprint Estimation

Simplified screening calculation for downwind distance to LFL (natural gas, LFL = 5%):

Rough screening formula (Gaussian plume, ground-level release): X_LFL ≈ K × (ṁ / (u × C_LFL))^0.5 Where: X_LFL = Downwind distance to LFL (m) K = Empirical constant (5-10 depending on stability) ṁ = Mass release rate (kg/s) u = Wind speed (m/s) C_LFL = LFL concentration (kg/m³) Example: Medium hole (1-inch) releasing 11.3 lb/s = 5.1 kg/s Natural gas: LFL = 5% by volume At ambient, 5% methane by volume ≈ 0.04 kg/m³ Wind speed u = 2 m/s (light wind, conservative) Stability class F (stable, worst case): K ≈ 8 X_LFL ≈ 8 × (5.1 / (2 × 0.04))^0.5 X_LFL ≈ 8 × (63.8)^0.5 X_LFL ≈ 8 × 7.99 X_LFL ≈ 64 meters = 210 feet For large hole (4-inch, ṁ = 180 lb/s = 81.8 kg/s): X_LFL ≈ 8 × (81.8 / (2 × 0.04))^0.5 = 8 × 32.0 = 256 meters = 840 feet Note: This is simplified screening only. Use PHAST, ALOHA, or equivalent for regulatory submittals. High-pressure jet releases have longer reach due to momentum, requiring specialized jet dispersion models.

Emergency Response Planning

Leak rate calculations inform emergency shutdown (ESD) system design and response procedures:

Response Element Small Leak Medium Leak Large Leak/Rupture
Detection time Minutes to hours Seconds to minutes Immediate (< 1 sec)
ESD activation Manual (operator decision) Automatic (gas detector) Automatic (pressure/flow anomaly)
Isolation time target 5-15 minutes acceptable 1-3 minutes required < 30 seconds critical
Evacuation Localized (equipment area) Unit evacuation (200-500 ft) Site evacuation (1,000+ ft)
Emergency services On-site response sufficient Fire department standby Full emergency response (fire, hazmat, EMS)

Inventory at Risk (IAR)

Inventory Between Isolation Valves: For pipeline segment of length L and diameter D: V_pipe = π × D² / 4 × L Mass inventory = V_pipe × ρ Where ρ is density at line conditions (use real gas density). Example: 12-inch pipeline, 5 miles between ESD valves D = 1.0 ft (12-inch ID) L = 5 miles × 5,280 ft/mile = 26,400 ft V = π × 1.0² / 4 × 26,400 = 20,740 ft³ At 900 psig, 70°F, natural gas (SG = 0.6, MW = 17.5, Z = 0.89): ρ = (P × MW) / (Z × R × T) ρ = (914.7 × 17.5) / (0.89 × 10.73 × 529.67) ρ = 3.14 lb/ft³ Mass inventory = 20,740 ft³ × 3.14 lb/ft³ = 65,100 lb Standard volume = 65,100 / 17.5 × 379.5 = 1,412,000 scf = 1.4 MMscf Blowdown after isolation (12-inch rupture): Initial release rate = 1,622 lb/s (from API 581 rupture example) As pressure decays, release rate decreases proportionally: ṁ(t) ≈ ṁ_initial × (P(t) / P_initial) Typical blowdown to 10% initial pressure in 30-60 seconds for large rupture. Total release ≈ 50-70% of inventory before pressure drops below choking threshold. Expected release = 0.6 × 65,100 lb = 39,000 lb = 17.7 tons This forms a massive flammable cloud requiring wide evacuation zone.

Regulatory Requirements

  • EPA Risk Management Plan (RMP - 40 CFR 68): Facilities with threshold quantities of regulated substances must model worst-case and alternative release scenarios
  • OSHA PSM (29 CFR 1910.119): Process Hazard Analysis (PHA) must identify and quantify potential releases
  • DOT Pipeline Safety (49 CFR 192): Integrity Management requires consequence modeling for High Consequence Areas (HCA)
  • State/local regulations: California CUPA, Texas RRC, and other state agencies may have additional modeling requirements
Emergency planning zones: Modern practice establishes graduated response zones based on dispersion modeling: (1) Immediate hazard zone (IDLH or > UFL), (2) Evacuation zone (LFL to UFL or toxic threshold), and (3) Shelter-in-place zone (below LFL/toxic but observable). Leak rate calculations are the foundation for determining these critical distances.

Common Pitfalls

  • Assuming unchoked flow for atmospheric release: Most high-pressure releases are choked; using unchoked equation underestimates rate by 30-50%
  • Using Cd = 1.0 for all scenarios: Sharp-edged holes have Cd ≈ 0.6-0.65; using 1.0 overpredicts by 50%
  • Ignoring Joule-Thomson cooling: High-pressure gas expands and cools (10-50°F drop); affects density and dispersion buoyancy
  • Neglecting terrain and obstacles: Gaussian plume models assume flat terrain; CFD required for complex sites
  • Using daytime meteorology for worst-case: Stable nighttime conditions (class F, low wind) produce longest downwind distances
  • Not accounting for inventory depletion: Leak rate decays as pressure drops after isolation; transient modeling required for time-integrated consequence