NGL & Cryogenic Processing

Economizer in Cryogenic NGL Recovery

Fundamentals of economizer design and operation in cryogenic natural gas liquid recovery plants. Covers Joule-Thomson valve positioning, feed-effluent heat exchange, cold box integration, approach temperature selection, and the role of economizers in maximizing NGL recovery efficiency.

Typical Approach

5–10 °F

Cold end approach temperature in gas-gas exchangers.

Energy Recovery

70–90%

Cold energy recovered from residue gas stream.

Operating Range

−150 °F

Typical coldest temperature in cryogenic plants.

1. Economizer Overview

An economizer in a cryogenic NGL recovery plant is a heat exchanger that recovers cold energy from the process effluent streams to pre-cool the incoming feed gas. This internal heat recovery reduces the external refrigeration or expansion work required to achieve the target cold temperatures, dramatically improving the energy efficiency and economics of the plant.

Why Economizers Are Essential

Without economizers, all the cold energy in the residue gas and NGL product streams would be wasted as these streams are warmed to pipeline or storage temperatures. In a typical cryogenic plant processing 200 MMscfd, the economizer system recovers the equivalent of 2,000–5,000 HP of refrigeration, which would otherwise need to be supplied by external refrigeration compressors or additional turboexpander capacity. The economizer is therefore the single most impactful piece of equipment for plant energy efficiency.

Role in the Process

Function Description Benefit
Feed gas pre-cooling Cools incoming feed gas against cold residue gas Reduces external refrigeration requirement
Residue gas warming Warms cold residue gas to pipeline temperature Meets pipeline delivery temperature specification
NGL product cooling Sub-cools NGL product for storage stability Reduces flash losses in downstream storage
Reflux generation Provides cold reflux to demethanizer column Improves C2+ or C3+ recovery

Types of Economizer Heat Exchangers

Type Application Temperature Range
Brazed aluminum (BAHX) Primary gas-gas and gas-liquid exchangers in cold box −269°C to +65°C (−452°F to +150°F)
Printed circuit (PCHE) High-pressure gas-gas service; compact installations −200°C to +900°C (−328°F to +1650°F)
Shell and tube Warm end exchangers; kettle reboilers for demethanizer −100°C to +300°C (−148°F to +572°F)
Plate-fin (wound coil) Large LNG and deep NGL recovery plants −269°C to +65°C

2. Thermodynamic Basis

The economizer operates on the fundamental principle that heat flows from hot to cold. The feed gas (warm) transfers heat to the process effluent streams (cold), simultaneously cooling the feed and warming the effluent. The exchanger is constrained by the second law of thermodynamics: the cold stream outlet temperature can never reach the hot stream inlet temperature.

Energy Balance

Q = mhot × Cphot × (Thot,in − Thot,out)

Q = mcold × Cpcold × (Tcold,out − Tcold,in)

Where Q = heat duty (BTU/hr), m = mass flow rate (lb/hr), Cp = heat capacity (BTU/lb·°F)

Effectiveness

ε = Qactual / Qmax

Qmax = (mCp)min × (Thot,in − Tcold,in)

Typical economizer effectiveness: 0.85–0.95

Phase Change Effects

In cryogenic NGL processing, the feed gas undergoes partial condensation as it cools through the economizer. This phase change releases latent heat, which significantly increases the total heat duty compared to a purely sensible heat exchange. The heat capacity of the condensing feed gas stream is not constant and must be evaluated using process simulation (HYSYS, ProMax) at multiple temperature intervals to accurately size the exchanger. Simple LMTD calculations assuming constant Cp will significantly undersize the economizer.

Temperature-Heat Duty Diagram

The composite heating and cooling curves plotted on a temperature vs. cumulative heat duty diagram reveal the minimum temperature approach (pinch point) and the thermodynamic feasibility of the heat exchange. The pinch point constrains the maximum heat recovery achievable.

Diagram Feature Significance
Pinch point Location of minimum approach temperature; limits heat recovery
Curve crossing Indicates thermodynamic infeasibility; design must be modified
Wide approach (warm end) Heat available but not utilized; opportunity for additional recovery
Phase change plateau Flat region on cooling curve where condensation occurs

3. Feed-Effluent Heat Exchange

The primary economizer function is feed-effluent exchange, where the cold residue gas leaving the demethanizer column (or cold separator) cools the incoming treated feed gas. This is the largest single heat exchange service in the plant.

Typical Stream Conditions

Stream Inlet Temp (°F) Outlet Temp (°F) Pressure (psig)
Feed gas (hot side) 80 to 100 −30 to −80 800–1,100
Residue gas (cold side) −100 to −150 50 to 80 250–450
NGL product (cold side) −50 to −100 60 to 90 300–600

CO2 Freeze-Out Risk

Carbon dioxide in the feed gas can freeze (solidify) at temperatures below approximately −109°F (−78.5°C) at typical processing pressures. CO2 freeze-out in economizer passages causes blockage, reduced heat transfer, flow maldistribution, and potential mechanical damage to brazed aluminum exchangers. Feed gas CO2 content must be reduced to 1–2 mol% (or lower for deep ethane recovery) before entering the cryogenic section. Process simulation must verify that no point in the economizer reaches the CO2 solid formation temperature at the local pressure and composition.

Multi-Stream Exchangers

Brazed aluminum heat exchangers (BAHX) can accommodate multiple streams simultaneously in separate passages within a single core. A typical cryogenic economizer may have 3–6 streams exchanging heat within one cold box assembly.

Stream Direction Phase
Inlet feed gasHot → ColdGas, then partial condensation
Residue gas from demethanizerCold → HotGas
NGL product from demethanizerCold → HotLiquid
Demethanizer refluxHot → ColdLiquid sub-cooling
Side reboiler dutyHot → ColdBoiling liquid return to column

4. Joule-Thomson Valve Positioning

The Joule-Thomson (JT) valve creates the cold temperatures needed for NGL condensation by expanding high-pressure gas through an isenthalpic throttling process. The position of the JT valve relative to the economizer determines the process configuration and the NGL recovery efficiency.

JT Before Economizer

Aspect Description
Process Feed gas expands through JT valve first, then enters economizer cold side
Temperature Maximum cooling achieved immediately; cold two-phase flow enters exchanger
Advantage Simple configuration; good for moderate NGL recovery
Disadvantage Two-phase flow in exchanger reduces heat transfer; poor distribution

JT After Economizer (Pre-Cooled Expansion)

Aspect Description
Process Feed gas pre-cooled in economizer, then expanded through JT valve
Temperature Pre-cooling shifts JT expansion to lower starting temperature
Advantage Deeper cooling; higher NGL recovery; better exchanger performance
Disadvantage Two exchangers or two zones needed; more complex piping

Turboexpander vs. JT Valve

Modern cryogenic NGL recovery plants predominantly use turboexpanders rather than JT valves for the primary expansion. Turboexpanders achieve isentropic (rather than isenthalpic) expansion, producing colder outlet temperatures for the same pressure ratio and recovering useful work to drive a compressor. A turboexpander plant typically achieves 10–15% higher ethane recovery than an equivalent JT plant at the same inlet conditions. The economizer design principles remain the same regardless of expansion device type, but the stream temperatures and duties differ.

5. Cold Box Design

The cold box is an insulated enclosure containing the brazed aluminum heat exchangers and associated cryogenic piping. The cold box protects the exchangers from ambient heat gain and moisture ingress, which could cause ice formation and blockage.

Cold Box Components

Component Purpose Design Notes
BAHX cores Multi-stream heat exchange Aluminum alloy 3003; brazed construction; rated to −452°F
Insulation Minimize heat leak from ambient Perlite fill (expanded volcanic glass); inert gas purge
Steel enclosure Contain insulation; support exchangers Carbon steel shell; weather-tight; access panels
Nozzle transitions Connect aluminum exchanger to steel piping Bi-metallic (aluminum-to-stainless) transition joints
Nitrogen purge Keep insulation dry; inert atmosphere Continuous or intermittent N2 supply; moisture monitoring

Mercury in Feed Gas

Trace mercury in natural gas is extremely damaging to brazed aluminum heat exchangers. Mercury amalgamates with aluminum, causing liquid metal embrittlement and catastrophic structural failure. Mercury removal to below 0.01 micrograms per normal cubic meter is required upstream of the cold box. Mercury removal units (MRU) using sulfur-impregnated activated carbon are standard upstream of all cryogenic plants processing mercury-containing gas.

6. Approach Temperature Selection

The approach temperature (the minimum temperature difference between the hot and cold streams in the exchanger) is a critical design parameter that balances capital cost (exchanger size) against operating cost (energy efficiency).

Approach Temperature Guidelines

Service Typical Approach (°F) Typical Approach (°C) Notes
Gas-gas (cryogenic cold end) 3–10 2–6 Tight approach justified by high cold energy value
Gas-gas (warm end) 10–25 6–14 Wider approach acceptable; lower temperature driving force value
Gas-boiling liquid (reboiler) 5–15 3–8 High heat transfer coefficient on boiling side
Condensing-gas 5–15 3–8 Phase change enhances heat transfer

Economic Optimization

Reducing the approach temperature increases the exchanger surface area (and cost) but reduces the external energy requirement. The optimal approach temperature minimizes the sum of annualized capital cost and annual operating cost. At current compression costs, the economic optimum for cryogenic gas-gas exchangers is typically 3–8°F. Below 3°F, the exchanger cost increases exponentially with diminishing energy savings. Above 10°F, the increased compression cost dominates.

7. Process Configurations

The economizer configuration varies depending on the NGL recovery target (ethane rejection vs. recovery), plant capacity, inlet gas composition, and the expansion device (JT valve or turboexpander).

Common Cryogenic Plant Configurations

Configuration C2 Recovery C3 Recovery Key Economizer Feature
Simple JT 15–30% 60–75% Single feed-residue exchanger
JT with external refrigeration 30–50% 80–90% Two-stage cooling: propane chiller + JT
Turboexpander (GSP) 80–90% 98%+ Multi-stream cold box with side reboilers
Enhanced turboexpander (RSV, OHR) 90–97% 99%+ Subcooled reflux generation; additional cold recovery
Ethane rejection mode 1–5% 95–99% Warmer cold box temperatures; modified stream routing

GSP (Gas Subcooled Process) Economizer

The GSP process, widely used for ethane recovery, uses the economizer to generate subcooled liquid reflux for the demethanizer column. A portion of the feed gas is condensed and subcooled in the cold box, then flashed to low pressure as reflux to the top of the demethanizer. The cold box must handle three or more streams: feed gas cooling, residue gas warming, and reflux sub-cooling.

Dual-Mode Operation

Many modern plants are designed to switch between ethane recovery and ethane rejection modes in response to NGL market prices. The economizer must accommodate both operating modes with different flow distributions, temperatures, and duties. This flexibility requires careful design of the cold box with appropriate stream bypasses and control valves to manage the transition between modes without shutting down the plant.

8. Operational Considerations

Economizer performance directly impacts plant NGL recovery, residue gas delivery temperature, and overall energy efficiency. Monitoring and maintaining economizer performance is essential for optimal plant operations.

Performance Monitoring

Parameter Monitoring Method Warning Sign
Approach temperature Inlet/outlet temperature measurements Increasing approach indicates fouling or flow maldistribution
Pressure drop Differential pressure transmitters Rising ΔP suggests fouling, hydrate, or CO2 freeze
UA product Calculated from duty and LMTD Declining UA indicates reduced heat transfer effectiveness
Cold box insulation External surface temperature survey Hot spots indicate insulation settling or moisture ingress

Common Operational Issues

Issue Cause Mitigation
CO2 freeze-out Excessive CO2 in feed; operation below freeze temperature Upstream amine treating; temperature monitoring; operating limits
Hydrate formation Water in feed gas above hydrate formation conditions Upstream dehydration to <1 lb/MMscf; glycol injection
Mercury damage Trace mercury amalgamation with aluminum Mercury removal unit upstream; periodic monitoring
Thermal stress Rapid temperature changes during startup/shutdown Controlled warm-up/cool-down rates per manufacturer limits
Flow maldistribution Fouling in individual passages; two-phase flow Proper header design; periodic cleaning; inlet separation

Startup and Shutdown Procedures

Brazed aluminum exchangers are sensitive to thermal shock. Temperature change rates must be limited to the manufacturer's specified maximum (typically 1–3°F per minute) during startup, shutdown, and mode transitions. Exceeding these rates can cause differential thermal expansion between the aluminum fins and the parting sheets, leading to fin debonding, internal leaks, and potential catastrophic failure. Automated startup sequences with temperature-controlled ramp rates are standard practice.

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