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Gas Hydrate Formation Prediction

GPSA · Katz · Baillie-Wichert

Hydrate Formation Predictor — Predicts hydrate formation temperature using Katz (sweet gas) and Baillie-Wichert (sour gas) methods per GPSA Section 20. Calculates inhibitor depression using Hammerschmidt equation for methanol, MEG, or DEG.

Operating Conditions

psig
°F
air=1
SG range: 0.55 (dry) to 0.80 (rich gas)

Prediction Method

mol%
mol%
Note: H₂S and CO₂ RAISE hydrate temperature (per GPSA Figure 20-8). Use Baillie-Wichert for >1% H₂S or >3% CO₂.

Hydrate Prevention

wt%
Typical Ranges (Hammerschmidt):
• Methanol: 20-50 wt% (15-45°F depression)
• MEG: 40-70 wt% (20-50°F depression)
• DEG: 50-70 wt% (limited use)

About This Calculator

Predicts gas hydrate formation temperature and calculates thermodynamic inhibitor requirements per GPSA.

Methods:

  • Katz (1959): Sweet gas P-T curve from GPSA Figure 20-4
  • Baillie-Wichert: Sour gas correction for H₂S/CO₂
  • Hammerschmidt: Inhibitor depression equation

Key Points:

  • Hydrates form when T < T_hydrate at given P
  • Maintain 10-15°F safety margin
  • Accuracy: ±5°F for sweet gas, ±3-5°F with inhibitor